東京科学大学　総合研究院　元素戦略MDXセンター　北野研究室　
(MDX Research Center for Element Strategy, Institute of Integrated Research,
Institute of Science Tokyo, Kitano Lab.)　　　　　　　　　　　　　　　　　　　

ホームメンバー 研究内容研究業績写真研究室生活
    増田 晋也 (Shinya Masuda) 
ResearcherID: ABA-9935-2020
ORCID: https://orcid.org/0000-0002-6319-3503
Google Scholar
Researchmap: https://researchmap.jp/shinya_masuda
  
学歴 / Education 　　　　　　 　　     
～2012年3月
Until March 2012		 徳島県立城東高校
Tokushima Prefectural Joto High School
2012年4月～2016年3月
April 2012 – March 2016		 大阪大学　工学部　応用理工学科
Division of Mechanical, Materials and Manufacturing Science, School of Engineering, Osaka University
2016年4月～2018年3月
April 2016 – March 2018		 大阪大学大学院　工学研究科　マテリアル生産科学専攻　博士前期課程
Master Course, Department of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University
2018年4月～2020年3月
April 2018 – March 2020		 大阪大学大学院　工学研究科　マテリアル生産科学専攻　博士後期課程
Doctor Cource, Department of Materials and Manufacturing Science, Graduate School of Engineering, Osaka University
学位 / Degree  
博士（工学）
Doctor of Engineering		 2020年3月　大阪大学　
（指導教員：山下弘巳　教授）
March 2020, Osaka University (Supervisor: Prof. Hiromi Yamashita)		  
職歴 / Professional Experience  
2019年4月～2020年3月
April 2019 – March 2020		 独立行政法人日本学術振興会, 特別研究員（DC2）
Research Fellow (DC2), Japan Society for the Promotion of Science (JSPS)
2020年4月～2020年4月
April 2020		 独立行政法人日本学術振興会, 特別研究員（PD）
Research Fellow (PD), Japan Society for the Promotion of Science (JSPS)
2020年4月～2025年5月
April 2020 – May 2025		 東京大学, 大学院理学系研究科化学専攻, 特任助教
Specially-Appointed Assistant Professor, Department of Chemistry, Graduate School of Science, The University of Tokyo
2025年5月～2025年8月
May 2025 – August 2025		 東京大学, 大学院理学系研究科化学専攻　助教
Assistant Professor, Department of Chemistry, Graduate School of Science, The University of Tokyo
2025年9月～現在
September 2025 – Present		 東京科学大学　総合研究院　元素戦略MDX研究センター　助教
Assistant Professor, MDX Research Center for Element Strategy, Institute of Integrated Research, Institute of Science Tokyo
   
受賞歴 / Awards  
2016年8月31日 第10回触媒道場ポスター賞
2017年5月13日 Excellent Research Award（2017 China-Japan Bilateral Photocatalysis Symposium）
2017年7月18日 平成29年度関西分析研究会優秀講演賞
2017年10月31日 NENCS Poster Award (Student)（International Symposium on Novel Energy Nanomaterials, Catalysts and Surfaces for Future Earth (NENCS)）
2018年11月27日 第28回キャラクタリゼーション講習会優秀ポスター発表賞 
2018年11月29日 第34回ゼオライト研究発表会若手優秀講演賞
2019年12月20日 Excellent Research Award (Osaka-Shanghai Joint Workshop for Energy/Environmental Materials and Applications (JWEEMA2019))
2021年 2021年度「貴金属に関わる研究助成金」萌芽賞（田中貴金属記念財団）
   
 

原著論文 / Original Research Articles

2026

  1. “Water-Soluble Gold Ultrathin Nanorods with NIR-II Longitudinal Localized Surface Plasmon Resonance and Improved Stability”Subarna Maity, Shinya Masuda, Shinjiro Takano*, and Tatsuya Tsukuda*Nanoscale (2026). DOI: 10.1039/D6NR02342H
  2. “Solubility-Mediated Access to a Diverse Series of Atomically Precise Gold Nanoclusters Protected by p-Mercaptobenzoic Acid”Shinya Masuda*, Wataru Ishii, Sami Malola, Shinjiro Takano, Takuya Nakashima, Hannu Häkkinen*, and Tatsuya Tsukuda*J. Am. Chem. Soc. (2026). DOI: 10.1021/jacs.6c10039
  3. “Critical Size of Gold Nanocluster Catalysts for Aerobic α,β-Dehydrogenation of β-Aminoketones Arising from Their Bidentate Metalation”Kosuke Sakamoto, Shinya Masuda*, Takafumi Yatabe*, Shinjiro Takano, Kazuya Yamaguchi*, and Tatsuya Tsukuda*ACS Catal., 16, 9963–9971 (2026). DOI: 10.1021/acscatal.6c00333
  4. “Effects of Phosphine Ligand Denticity on Catalytic Activity and Durability of Gold Nanoparticles in the Oxidation of Benzyl Alcohol”Yiwei Wu, Shinya Masuda, Kosuke Sakamoto, Haru Hirai, Shinjiro Takano, and Tatsuya Tsukuda*Nanoscale, 18, 2837–2843 (2026). DOI: 10.1039/D5NR03975D

2025

  1. “Negative Electron Binding Energy of the Au13 Core in Au25(SC6H4CO2H)18 Achieved by Ligand Deprotonations”Shun Ito, Yuki Fujiwara, Theresa Mohr, Shinya Masuda, Kiichirou Koyasu, Manfred Kappes, and Tatsuya Tsukuda*J. Phys. Chem. Lett., 16, 8531–8535 (2025). DOI: 10.1021/acs.jpclett.5c01987
  2. “Aqueous-Phase Synthesis of Benzyl Ester over Partially Thiolated Au25 Nanocluster Catalysts: Improving Selectivity with a Hydrophobic Carbon Support”Kosuke Sakamoto, Koki Chida, Shinya Masuda*, Takeharu Yoshii*, Hirotomo Nishihara, and Tatsuya Tsukuda*Green Chem., 27, 8133–8142 (2025). DOI: 10.1039/D5GC01292A

2024

  1. “Substrate-Dependent Role of a Pd Dopant in PdAu12 Catalysts in the Oxidation of p-Substituted Benzyl Alcohols: Promotion of Hydride Abstraction and Reductive Activation of O2”Shinya Masuda*, Haru Hirai, Pei Zhao, Shinjiro Takano, Masahiro Ehara, and Tatsuya Tsukuda*ACS Catal., 14, 17123–17131 (2024). DOI: 10.1021/acscatal.4c03871
  2. “Carbon-Supported Au25 Cluster Catalysts Partially Decorated with Dendron Thiolates: Enhanced Loading Weight and Durability for Hydrogen Evolution Reaction”Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano, and Tatsuya Tsukuda*Nanoscale, 16, 20608–20616 (2024). DOI: 10.1039/d4nr03385j
  3. “Blue Shift of Localized Surface Plasmon Resonance of Gold Ultrathin Nanorod by Forming a Single Atomic Silver Shell via Antigalvanic Process”Subarna Maity, Toshiki Komagata, Shinjiro Takano, Shinya Masuda, Jun Kikkawa, Koji Kimoto, Koji Harano* and Tatsuya Tsukuda*Nano Lett., 24, 13206–13212 (2024). Supplementary Cover DOI: 10.1021/acs.nanolett.4c03159
  4. “Introducing Iodide Ligands on IrAu12 Cluster Enhances Phosphorescence Efficiency and Photoredox Activity”Hirai Haru, Shinjiro Takano, Shinya Masuda and Tatsuya Tsukuda*ChemElectroChem, 11, e202300669 (2024). DOI: 10.1002/celc.202300669
  5. “Pt-Doped Ru Nanoparticles Loaded on ‘Black Gold’ Plasmonic Nanoreactors as Air Stable Reduction Catalysts”Gunjan Sharma, Rishi Verma, Shinya Masuda, Khaled Mohamed Badawy, Nirpendra Singh, Tatsuya Tsukuda* and Vivek Polshettiwar*Nat. Commun., 15, 713 (2024). DOI: 10.1038/s41467-024-44954-4

2023

  1. “Partially Thiolated Aun (n = 25, 102) Clusters on Layered Double Hydroxide Anchored by Electrostatic Interaction: Size Effect on 5-Hydroxymethylfurfural Oxidation Catalysis”Shinya Masuda* and Tatsuya Tsukuda*ACS Catal., 13, 16179–16187 (2023). DOI: 10.1021/acscatal.3c03323
  2. “Au13 Superatom Bearing Two Terpyridines at Coaxial Positions: Photoluminescence Quenching via Complexation with 3d Metal Ions”Naoki Kito, Shinjiro Takano, Shinya Masuda, Koji Harano and Tatsuya Tsukuda*Bull. Chem. Soc. Jpn., 96, 1045–1051 (2023). DOI: 10.1246/bcsj.20230148
  3. “Partially Thiolated Au25 Cluster Anchored on Carbon Support via Noncovalent Ligand-Support Interactions: Active and Robust Catalyst for Aerobic Oxidation of Alcohols”Kosuke Sakamoto, Shinya Masuda, Shinjiro Takano and Tatsuya Tsukuda*ACS Catal., 13, 3263–3271 (2023). DOI: 10.1021/acscatal.2c06197

2022

  1. “Synergistically Activated Pd Atom in Polymer-Stabilized Au23Pd1 Cluster”Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano, Jun Kikkawa and Tatsuya Tsukuda*ACS Nano, 16, 16932–16940 (2022). DOI: 10.1021/acsnano.2c06996
  2. “Revealing Hydrogen Spillover Pathways in Reducible Metal Oxides”Kazuki Shun, Kohsuke Mori*, Shinya Masuda, Naoki Hashimoto, Yoyo Hinuma, Hisayoshi Kobayashi and Hiromi Yamashita*Chem. Sci., 13, 8137–8147 (2022). DOI: 10.1039/d2sc00871h
  3. “Polymer-Stabilized Au38 Cluster: Atomically Precise Synthesis by Digestive Ripening and Characterization of the Atomic Structure and Oxidation Catalysis”Shingo Hasegawa, Shinya Masuda, Shinjiro Takano, Koji Harano and Tatsuya Tsukuda*ACS Catal., 12, 6550–6558 (2022). DOI: 10.1021/acscatal.2c01355
  4. “Synthesis of Active, Robust and Cationic Au25 Cluster Catalysts on Double Metal Hydroxide by Long-Term Oxidative Aging of Au25(SR)18”Shinya Masuda, Shinjiro Takano, Seiji Yamazoe and Tatsuya Tsukuda*Nanoscale, 14, 3031–3039 (2022). DOI: 10.1039/D1NR07493H

2021

  1. “Decorating an Anisotropic Au13 Core with Dendron Thiolates: Enhancement of Optical Absorption and Photoluminescence”Tsubasa Omoda, Shinjiro Takano, Shinya Masuda and Tatsuya Tsukuda*Chem Commun., 57, 12159–12162 (2021). DOI: 10.1039/d1cc05235g
  2. “Synergistic Effect in Ir- or Pt-Doped Ru Nanoparticles: Catalytic Hydrogenation of Carbonyl Compounds under Ambient Temperature and H2 Pressure”Shotaro Matsuda, Shinya Masuda, Shinjiro Takano, Nobuyuki Ichikuni and Tatsuya Tsukuda*ACS Catal., 11, 10502–10507 (2021). DOI: 10.1021/acscatal.1c02703
  3. “Few-nm-Sized, Phase-Pure Au5Sn Intermetallic Nanoparticles: Synthesis and Characterization”Satoshi Osugi, Shinjiro Takano, Shinya Masuda, Koji Harano and Tatsuya Tsukuda*Dalton Trans., 50, 5177–5183 (2021). DOI: 10.1039/d1dt00132a

2020

  1. “Interconversion of Formate/Bicarbonate for Hydrogen Storage/Release: Improved Activity Following Sacrificial Surface Modification of a Ag@Pd/TiO2 Catalyst with a TiOx Shell”Shinya Masuda, Yuki Shimoji, Kohsuke Mori*, Yasutaka Kuwahara, and Hiromi Yamashita*ACS Appl. Energy Mater., 3, 5819–5829 (2020). DOI: 10.1021/acsaem.0c00744
  2. “Additive-Free Aqueous Phase Synthesis of Formic Acid by Direct CO2 Hydrogenation over a PdAg Catalyst on a Hydrophilic N-Doped Polymer–Silica Composite Support with High CO2 Affinity”Shinya Masuda, Kohsuke Mori*, Yasutaka Kuwahara, Catherine Louis and Hiromi Yamashita*ACS Appl. Energy Mater., 3, 5847–5855 (2020). DOI: 10.1021/acsaem.0c00771
  3. “Synthesis of a Binary Alloy Nanoparticle Catalyst with an Immiscible Combination of Rh and Cu Assisted by Hydrogen Spillover on a TiO2 support”Shinya Masuda, Kazuki Shun, Kohsuke Mori*, Yasutaka Kuwahara, and Hiromi Yamashita*Chem. Sci., 11, 4194–4203 (2020). DOI: 10.1039/c9sc05612b
  4. “PdAg Nanoparticles and Aminopolymer Confined within Mesoporous Hollow Carbon Spheres as an Efficient Catalyst for Hydrogenation of CO2 to Formate”Guoxiang Yang, Yasutaka Kuwahara, Shinya Masuda, Kohsuke Mori, Catherine Louis, and Hiromi Yamashita*J. Mater. Chem. A, 8, 4437–4446 (2020). DOI: 10.1039/c9ta13389e

2019

  1. “Controlled Release of Hydrogen Isotope Compounds and Tunneling Effect in the Heterogeneously-Catalyzed Formic Acid Dehydrogenation”Kohsuke Mori*, Yuya Futamura, Shinya Masuda, Hisayoshi Kobayashi, and Hiromi Yamashita*Nat. Commun., 10, 4094–4103 (2019). DOI: 10.1038/s41467-019-12018-7
  2. “PdAg Nanoparticles Supported on Resorcinol-Formaldehyde Polymers Containing Amine Groups: the Promotional Effect of phenylamine Moieties on CO2 Transformation to Formic acid”Shinya Masuda, Kohsuke Mori*, Yasutaka Kuwahara, and Hiromi Yamashita*J. Mater. Chem. A, 7, 16356–16363 (2019). DOI: 10.1039/c9ta02552a

2018

  1. “Simple Route for the Synthesis of Highly Active Bimetallic Nanoparticle Catalysts with Immiscible Ru and Ni Combination by utilizing a TiO2 Support”Shinya Masuda, Kohsuke Mori*, Taiki Sano, Kohei Miyawaki, Wei-Hung Chiang, and Hiromi Yamashita*ChemCatChem, 10, 3526–3531 (2018). DOI: 10.1002/cctc.201800329
  2. “PdAg Nanoparticles Supported on Functionalized Mesoporous Carbon: Promotional Effect of Surface Amine Groups in Reversible Hydrogen Delivery/Storage Mediated by Formic Acid/CO2”Shinya Masuda, Kohsuke Mori*, Yuya Futamura, and Hiromi Yamashita*ACS Catal., 8, 2277–2285 (2018). DOI: 10.1021/acscatal.7b04099

2017

  1. “Palladium Copper Chromium Ternary Nanoparticles Constructed In situ within a Basic Resin: Enhanced Activity in the Dehydrogenation of Formic Acid”Kohsuke Mori*, Kohei Naka, Shinya Masuda, Kohei Miyawaki, and Hiromi Yamashita*ChemCatChem, 9, 3456–3462 (2017). Front Cover DOI: 10.1002/cctc.201700595
  2. “Phenylamine-Functionalized Mesoporous Silica Supported PdAg Nanoparticles: a Dual Heterogeneous Catalyst for Formic Acid/CO2-Mediated Chemical Hydrogen Delivery/Storage”Kohsuke Mori*, Shinya Masuda, Hiromasa Tanaka, Kazunari Yoshizawa, Michel Che, and Hiromi Yamashita*Chem. Commun., 53, 4677–4680 (2017). Inside Front Cover DOI: 10.1039/c7cc00864c

総説・解説・著書 / Reviews, Commentaries and Books

2026

  1. “Ligand Engineering for Active and Durable, Atomically-Precise Coinage-Metal Nanocluster Catalysts”Kosuke Sakamoto, Shinya Masuda, and Tatsuya Tsukuda*Coord. Chem. Rev., 566, 218136 (2026). DOI: 10.1016/j.ccr.2026.218136

2025

  1. “金クラスター担持触媒の精密組成制御による触媒特性評価”増田晋也まてりあ, 64, 244–249 (2025).
  2. “サイズが規定された金クラスター担持触媒の 堅牢化と酸化触媒機構の解明”増田晋也, 佃達哉触媒研究の動向と展望 (2025)

2024

  1. “Atomically precise Au and Ag nanoclusters doped with a single atom as model alloy catalysts”Shinya Masuda, Kosuke Sakamoto and Tatsuya Tsukuda*Nanoscale, 16, 4514–4528 (2024). Front Cover Image DOI: 10.1039/d3nr05857c
  2. “Bonding and electronic interactions of hydrogen with gold superatoms”Subarna Maity, Shinjiro Takano, Shinya Masuda and Tatsuya Tsukuda*J. Phys. Chem. C, 128, 19–30 (2024). Supplementary Cover Image DOI: 10.1021/acs.jpcc.3c07090
  3. “高耐久性担持金クラスター触媒の原子精度調製とサイズ特異的な酸化触媒機構の解明”増田晋也, 佃達哉触媒, 66, 87–93 (2024).

2023

  1. “Role of Surface-grafted Amine Groups on Carbon-based Support for Formic Acid/CO2-mediated Chemical Hydrogen Storage/Supply”Kohsuke Mori*, Shinya Masuda and Hiromi YamashitaCarbon Reports, 2, 206–213 (2023). DOI: 10.7209/carbon.020404

2020

  1. “非平衡合金ナノ粒子触媒によるアンモニアボランからの効率的水素生成”増田晋也, 森浩亮, 山下弘巳月刊ファインケミカル, Vol. 49, No. 6, 24-31 (2020)

2018

  1. “ギ酸を利用した水素エネルギーの貯蔵・輸送のための金属触媒”森浩亮, 増田晋也, 山下弘巳太陽エネルギー学会誌, 44, 15–21 (2018).